Hard Spheres and Polymers

Characterizing Hard Spheres

α₂ goes to ∞?

Line drawn is \(A \left(\phi^\star - \phi\right)^n\), where

\( \phi^\star = 0.6138 \pm 0.0031\) (jamming is at \(\phi^J = 0.634\pm0.004\) )

\( n = -2.08 \pm 0.19 \)

That would mean α₂ goes to ∞.

Aging

When we increase the density, it takes a long time to equilibrate.

How does α₂ react as we equilibrate?

Can we get an estimate of α₂ at even higher distances by studying non-equilibrium data?

Note: Plot shown is only a cartoon.

New Directions: Polymers

How do polymers such as RNA and DNA affect α₂?

  • Polymers may create micro-environments, leading to large α₂

  • Investigate the affect of polymer density and size on α₂ of particles

Example

Example: MSD

Example: α₂